• 姓名: 官宝红
  • 职称: 教授
  • 学位: 博士
  • 浙江大学
  • 环境与资源学院
教育背景

1989年中国地质大学地球化学系本科毕业

2001年浙江大学化学工程系研究生毕业,工学博士

工作经历

2001年开始在浙江大学环境与资源学院任教,2011年-2013年罗切斯特大学访问学者

现任环境工程研究所副所长

学术成果

发明了多项工业废水和污水处理技术和设备,开发了均相催化多金属还原处理复杂和毒害性废水技术、非均相催化氧化深度处理污水和微污染水技术,实现了工程化、装备成套化和市场推广,被推荐为国家科技惠民计划优秀成果、国家重点环境保护实用技术、国家节能减排技术、浙江先进适用废水处理技术、浙江省“五水共治”适用技术。发明了脱硫石膏高值资源化常压盐溶液法制备α半水石膏的工艺技术,开发了下游系列二次产品,建立了国内外首套中试装置,生产出高品质α半水石膏,起草了国家行业标准。解决了多介质中石膏相变热力学、结晶动力学和形貌调控关键理论问题,发展了胶凝强度发育理论,构建了α半水石膏粉末级配与强度模型,建立了新的制备技术和理论开发工具。

政府推荐技术

[1] 科技部,科技惠民计划先进科技成果,均相催化还原法处理有机氯化物工业废水,2012;申报单位:浙江大学;第一完成人。

[2] 环保部,国家重点环境保护实用技术,均相催化还原法处理有机氯化物工业废水,2012;申报单位:浙江大学,杭州浙大易泰环境科技有限公司;第一完成人。

[3] 浙江省环保厅,浙江环境保护先进适用技术,印染染色废水高级催化氧化降解脱色与回用技术,2013;申报单位:浙江大学,杭州浙大易泰环境科技有限公司;第一完成人。

[4] 浙江省“五水共治”适用技术,均相催化还原脱氯废水处理技术,2014,申报单位:浙江大学,第一完成人。

[5] 浙江省“五水共治”适用技术,印染废水深度处理与脱色技术,2014,申报单位:杭州浙大易泰环境科技有限公司,第一完成人。

[6] 浙江省“五水共治”适用技术,高级催化氧化深度降解达标保障技术,2014,申报单位:浙江大学,第一完成人。

[7] 浙江省“五水共治”适用技术,水/污水除臭技术,2014,申报单位:浙江大学,第一完成人。

科研项目

主持设计工业废水处理、中水回用、地表水修复工程

[1] 阿特维斯制药有限公司,化工制药废水, 2015.

[2] 建德市莲花镇林查水库,水体修复,2014-2015.

[3] 建德市莲花镇戴家水库,疏浚与水体修复,2014-2015.

[4] 建德五马洲工业集中式污水处理厂二期工程, 2014-2015.

[5] 海安城南化工有限公司,化工制药废水,2014-2015.

[6] 巨化集团汉正制药有限公司,化工制药废水,2014.

[7] 康恩贝集团丰登化工有限公司,化工废水,2014.

[8] 金华宏达染整有限公司,印染废水,2014.

[9] 金华光阳印染有限公司,印染废水,2013-2014.

[10] 金华东方线业有限公司,印染废水,2013-2014.

[11] 浙江真爱家居有限公司,印染废水,2013.

[12] 浙江巨宏工贸有限公司,重金属废水,2013.

[13] 桐庐金利针织有限公司,印染废水,2013.

[14] 台州椒江星明印染厂,印染废水,2013.

[15] 浙江新星月印染有限公司,印染废水,2013.

[16] 台州市恒虹砂洗有限公司,印染废水,2013.

[17] 江苏盐化集团公司,氯苯化工废水,2012.

[18] 巨化集团氟化厂,氨氮化工废水,2011.

[19] 巨化集团电化厂,氯碱化工废水,2010.

[20] 山东东岳化工集团公司,氯碱化工废水,2011.

[21] 浙江三美化工有限公司,甲烷氯化物废水,2009.

[22] 金华金东区电镀企业联片治理,电镀废水,2009.

[23] 浙江顺达高分子材料有限公司,化工废水,2009.

[24] 京杭运河杭州段21条支流,污染调查与评估,2006-2008.

[25] 浙江圣山实业有限公司,印染废水,2006.

[26] 巨化集团氟化厂,甲烷氯化物废水,2006.

[27] 京杭运河杭州段主航道污染调查与评估,2003-2005.

[28] 浙江手心医药化学品有限公司,化工制药废水,2005.

论文专著

[1] Hailu Fu, Baohong Guana*, Zhongbiao Wu. Transformation Pathways from Calcium Sulfite to α-Calcium Sulfate Hemihydrate in Concentrated CaCl2 Solutions. Fuel, 2015. In Press.

[2] Guangming Jiang, Qiaoshan Chen, Sen Zhang, Caiyun Jia, Zhongbiao Wu, Baohong Guan. Controlled Synthesis of Monodisperse α-Calcium Sulfate Hemihydrate Nanoellipsoids. Physical Chemistry Chemical Physics, 2015. In Press.

[3] Jingwei Mao, Guangming Jiang, Qiaoshan Chen, Baohong Guan*. Influences of citric acid on the metastability of α-calcium sulfate hemihydrate in CaCl2 solution. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2014: 443(20): 265–271.

[4] Hailu Fu, Guangming Jiang, Hao Wang, Zhongbiao Wu, Baohong Guan*. Solution mediated transformation kinetics of calcium sulfate dihydrate to α-calcium sulfate hemihydrate in CaCl2 solutions at elevated temperature. Industrial & Engineering Chemistry Research, 2013, 52 (48): 17134–17139.

[5] Jie Yu, Minhui Guo, Xinhua Xu, Baohong Guan*. The role of temperature and CaCl2 in activated sludge dewatering under hydrothermal treatment. Water Research, 2013, 50:10-17.

[6] Guangming Jiang, Hailu Fu, Keith Savino, Jiajing Qian, Zhongbiao Wu, Baohong Guan*. Nonlattice Cation-SO42- Ion Pairs in Calcium Sulfate Hemihydrate Nucleation. Crystal Growth and Design, 2013, 13(11): 5128-5134.

[7] Guangming Jiang, Jinwei Mao, Hailu Fu, Xu Zhou, Baohong Guang*. Insight Into Metastable Lifetime of α-Calcium Sulfate Hemihydrate in CaCl2 Solution. Journal of the American Ceramic Society, 2013, 96(10): 3265-3271.

[8] Jie Yu, Wenxia Liu, Aibin Zeng, Baohong Guan*, Xinhua Xu. Effect of SO42- on 1,1,1 - Trichloroethane Degradation by Fe0 in Aqueous Solution. Groundwater, 2013, 51(2): 286-292.

[9] Baohong Guan*, Bao Kong, Hailu Fu, Jie Yu, Guangming Jiang, Li Yang. Pilot scale preparation of α-calcium sulfate hemihydrate from FGD gypsum in Ca-K-Mg aqueous solution under atmospheric pressure. Fuel, 2012, 98: 48-54.

[10] Bao Kong, Jie Yu, Keith Savino, Yigang Zhua, Baohong Guan*. Synthesis of α-calcium sulfate hemihydrate submicron-rods in water/n-hexanol/CTAB reverse microemulsion. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2012, 409: 88- 93.

[11] Bao Kong, Baohong Guan*, Matthew Yates, Zhongbiao Wu. Control of α-calcium sulfate hemihydrate morphology using reverse microemulsions. Langmiur, 2012,, 28, 14137−14142.

[12] Hailu Fu, Baohong Guan, Guangming Jiang, Matthew Z. Yates, Zhongbiao Wu. Effect of supersaturation on competitive nucleation of CaSO4 phases in a concentrated CaCl2 solution. Crystal Growth and Design, 2012, 12 (3): 1388–1394.

[13] Baohong Guan*, Jie Yu, Hailu Fu, Minhui Guo, Xinhua Xu. Improvement of activated sludge dewaterability by mild thermal treatment in CaCl2 solution. Water research, 2012.12, 46(2): 425-432.

[14] Baohong Guan*, Li Yang, Hailu Fu, Bao Kong, Tingying Li, Liuchun Yang. α- Calcium sulfate hemihydrate preparation from FGD gypsum in recycling mixed salt solutions. Chemical Engineering Journal, 2011, 174: 296-303.

[15] Baohong Guan*, Guangming Jiang, Hailu Fu, Li Yang, Zhongbiao Wu. Thermodynamic preparation window of alpha calcium sulfate hemihydrate from calcium sulfate dihydrate in non-electrolyte glycerol-water solution under mild conditions. Industrial and Engineering Chemistry Research, 2011, 50: 13561–13567.

[16] Baohong Guan*, Guangming Jiang, Zhongbiao Wu, Jingwei Mao, Bao Kong. Preparation of a-calcium sulfate hemihydrate from calcium sulfate dihydrate in methanol-water solution under mild conditions. Journal of the American Ceramic Society, 2011, 94: 3261-3266.

[17] Baohong Guan*, Hailu Fu, Jie Yu, Guangming Jiang, Bao Kong. Direct transformaton of calcium sulfite to alpha-calcium sulfate hemihydrate in a concentrated Ca-Mg-Mn chlorid solution under atmospheric pressure. Fuel, 2011/1, 90: 36-41.

[18] Qingqing Ye, Baohong Guan*, Wenbin Lou, Li Yang, Bao Kong. Effect of particle size distribution on the hydration and compressive strength development of α-calcium sulfate hemihydrate paste. Powder Technology, 2011/2, 207: 208–214.

[19] Wenbin Lou, Baohong Guan*, Zhongbiao Wu. Dehydration behavior of FGD gypsum by simultaneous TG and DSC analysis. Journal of Thermal Analysis and Calorimetry, 2011/4, 104(2): 661-669.

[20] Baohong Guan, Liuchun Yang, Zhongbiao Wu. Effect of Mg2+ ions on the nucleation kinetics of calcium sulfate in concentrated calcium chloride solutions. Industrial and Engineering Chemistry Research, 2010/5, 49 (12), 5569-5574.

[21] Baohong Guan, Qingqing Ye, Jiali Zhang, Wenbin Lou, Zhongbiao Wu. Interaction between α-calcium sulfate hemihydrates and superplasticizer from the point of adsorption characteristics, hydration and hardening process. Cement and Concrete Research, 2010/2, 40: 253 - 259.

[22] Wenbin Lou, Baohong Guan*, Zhongbiao Wu. Calorimetric study of ternary binder of calcium aluminate cement, Portland-limestone cement and FGD gypsum, Journal of Thermal Analysis and Calorimetry, 2010/7, 101(1):119-127.

[23] Baohong Guan*, Qingqing Ye, Zhongbiao Wu, Wenbin Lou, Liuchun Yang. Analysis of the relationship between particle size distribution of alpha-calcium sulfate hemihydrate and compressive strength of set plaster-Using grey model. Powder Technology, 2010/6, 200(3): 136-143.

[24] Xiaoqin Wu, Wei He, Baohong Guan*, Zhongbiao Wu. Solubility of calcium sulfate dihydrate in Ca-Mg-K chloride salt solution in the range of (348.15 to 371.15) K. Journal of Chemical & Engineering Data, 2010/4, 55 (6): 2100–2107.

[25] Jiangjiang Pan, Baohong Guan*. Adsorption of nitrobenzene from aqueous solution on activated sludge modified by cetyltrimethylammonium bromide. Journal of Hazardous Materials, 2010/11, 183: 341-346.

[26] Bao Kong, Bao Hong Guan*, Liu Chun Yang. Influence of Seed Crystal and Modifier on the Morphology of α-calcium Sulfate Hemihydrate Prepared by Salt Solution Method in Pilot Scale, Advanced Materials Research, 2010/12, 168-170: 8-12.

[27] Baohong Guan, Liuchun Yang, Zhongbiao Wu, Zhuoxian Shen, Xianfa Ma, Qingqing Ye. Preparation of α-calcium sulfate hemihydrate from FGD gypsum in K, Mg-containing concentrated CaCl2 solution under mild conditions. Fuel, 2009/7, 88(7): 1286 - 1293.

[28] Liuchun Yang, Zhongbiao Wu, Baohong Guan*, Hailu Fu, Qingqing Ye. Growth rate of α-calcium sulfate hemihydrate in K-Ca-Mg-Cl-H2O systems at elevated temperature. Journal of Crystal Growth, 2009/10, 311(20): 4518 - 4524.

[29] Zhuoxian Shen, Baohong Guan*, Hailu Fu, Liuchun Yang. Effect of potassium sodium tartrate and sodium citrate on the preparation of a-calcium sulfate hemihydrate from flue gas desulfurization (FGD) gypsum in concentrated electrolyte solution. Journal of the American Ceramic Society, 2009/12, 92(12): 2894 - 2899.

[30] Baohong Guan, Weimin Ni, Zhongbiao Wu, Yong Lai. Removal of Mn(II) and Zn(II) Ions from Flue Gas Desulfurization Wastewater with Water-soluble Chitosan, Separation & Purification Technology, 2009/3/12, 65(3): 269-274.

[31] Liuchun Yang, Baohong Guan*, Zhongbiao Wu, Xianfa Ma. Solubility and phase transitions of calcium sulfate in KCl solutions between 85 °C and 100 °C. Industrial and Engineering Chemistry Research, 2009/7, 48(16): 7773 - 7779.

[32] Baohong Guan, Wenbin Lou, Qingqing Ye, Hailu Fu, Zhongbiao Wu. Calorimetric study of calcium aluminate cement blended with flue gas desulfurization gypsum. Journal of Thermal Analysis and Calorimetry, 2009/6, 98(3): 737 - 742.

[33] Baohong Guan*, Xianfa Ma, Zhongbiao Wu, Liuchun Yang, Zhuoxian Shen. Crystallization routes and metastability of α-calcium sulfate hemihydrate in potassium chloride solutions under atmospheric pressure. Journal of Chemical & Engineering Data, 2009/3, 54(3): 719–725.

[34] Zhong-biao Wu, Wei-min Ni and Bao-hong Guan*. Application of chitosan as flocculant for coprecipitation of Mn(II) and suspended solids from dual-alkali FGD regenerating process, Journal of Hazardous Materials, 2008/4, 152(2): 757–764.

[35] Baohong Guan*, Zhuoxian Shen, Zhongbiao Wu, Liuchun Yang, Xianfa Ma. Effect of pH on the preparation of α-calcium sulfate hemihydrate from FGD gypsum with the hydrothermal method. Journal of the American Ceramic Society, 2008/12, 91(12): 3835 - 3840.

[36] Meng Yafeng, Guan Baohong*, Wu Zhongbiao, Wang Dahui. Enhanced degradation of carbon tetrachloride by surfactant-modified zero-valent iron, Journal of Zhejiang University Science B, 2006/9, 7(9):702-707.

[37] Guan Bao-hong*. Stability of Expanded Granular Sludge Bed Process for Terylene Artificial Silk Printing and Dyeing Wastewater Treatment, Journal of environmental sciences, 2005/3, 17(3):419-424.

[38] GUAN Bao-hong*, WU Zhong-biao, XU Gen-liang. Kinetics of aerobically activated sludge on terylene artificial silk printing and dyeing wastewater treatment, Journal of Zhejiang University Science A, 2004/4, 5(4): 441-449.

[39] Guan Bao-hong*, Wu Zhong-biao, Wu Zu-ceng, Xu Gen-liang, and Tan Tian-en. Biodegradability of terephthalic acid in terylene artificial silk printing and dyeing wastewater, Journal of environmental sciences, 2003/1,15(3):296-301.

[40] MENG Ya-feng, GUAN Bao-hong*, WU Zhong-biao, WANG Da-hui. Enhanced degradation of carbon tetrachloride by surfactant-modified zero-valent iron. Journal of Zhejiang University Science B, 2006/9, 7(9):702-707.

专利成果

[1] 一种钙基污泥的脱水方法. 授权号: ZL 201110271626.2. 授权日期:2013.01.31.

[2] 以铝土矿与脱硫石膏为基料的自流平材料及其制备方法. 授权号:ZL 200910155268.1. 授权日期:2012.06.27

[3] 一种强化剩余活性污泥脱水性能的方法. 授权号: ZL 201210381224.2. 授权日期:2014.07.30.

[4] 一种以脱硫石膏和尿素为原料的溶液结晶法制备尿素石膏的技术. 受理号:201310026027.3. 授权中。

[5] 一种利用磷石膏为原料的溶液结晶法制备尿素磷石膏的方法. 授权号:ZL 201310025701.6. 授权日期:2014.07.30。

[6] 一种工业废水脱色处理工艺.授权号: ZL201110172779.1. 授权日期: 2011.06.24.

[7] 一种催化金属还原-絮凝沉淀法处理氯仿和四氯化碳工业废水工艺. 授权号: ZL03154176.3. 授权日期: 2006.2.22.

[8] 一种去除废水中有机氯化物的方法及设备. 授权号:ZL200610049204.X. 授权日期: 2008.10.29.

[9] 一种超声辅助强化金属还原有机氯化物脱氯的方法. 授权号: ZL200610050387.7. 授权日期:2008.7.2.

[10] 阳离子表面活性剂增强金属还原有机氯化物脱氯的方法. 授权号: ZL200610053042.7. 授权日期: 2008.7.2.

[11] 处理偏氯乙烯皂化废水的方法. 授权号: ZL200610053041.2. 授权日期: 2009.7.1.

[12] 一种脱硫石膏自流平材料及其制备方法. 授权号: ZL 200710069007.9, 授权日期: 2010.12.1.

[13] 在常压KCl溶液中将脱硫石膏转化为a-半水石膏的方法. 授权号: ZL 200810121470.8, 授权日期: 2011.4.27.

[14] 一种将剩余活性污泥制备成吸附剂的化学改性方法. 授权号: ZL200910096906.7, 授权日期: 2010.12.1.

[15] 抑制双碱法烟气脱硫浆液中有效脱硫组分催化氧化的方法. 授权号: ZL200910098248.5, 授权日期: 20110601.

[16] 一种二水石膏在盐溶液中制备α-半水石膏的控制方法. 授权号: 200910097993.8, 授权日期: 2010.6.1.

[17] 基于灰色模型优化颗粒级配提高石膏胶凝体强度的方法. 授权号: ZL200910096555.X, 授权日期: 20111207.

[18] 一种以醇水溶液为结晶介质制备α-半水石膏方法, 授权号: ZL201110159307.2, 授权日期: 2013.1.16.

[19] 一种防水保温轻质高强石膏板材及其制备方法, 授权号:ZL 201310120712.2, 授权日期:2014.11.20.

奖励/荣誉

[1] 高等学校科学技术进步奖,一等奖,教育部,2009.01,第三完成人。

[2] 浙江省科学技术奖,二等奖,浙江省人民政府,2005.12,第三完成人。

[3] 国家环境保护科学技术奖,二等奖,环境保护部,2013.12,第三完成人。

[4] 浙江省环境保护科学技术奖,二等奖,浙江省环保局,2007,第一完成人。